Duliajan College has a spacious Student Union Room having all types of necessary facilities. The Students' Union Room is the place from where the decisions made by the collective students' body are executed. The Students' Union Room is not just a space for a selected few; rather it is an open platform for all students to express their views and ideas.

The Duliajan College Student Union plays a vital role in representing the student body and organizing various activities and events throughout the academic year. They work towards enhancing the overall student experience by addressing student concerns, promoting extracurricular activities, and fostering a sense of community within the college. The union also collaborates with the college administration to ensure that student voices are heard in decision-making processes.

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